描述
PMMA1的物理性质
PMMA塑料材料
优良的透明度和优异的耐老化性
PMMA具有重量轻、成本低、易于成型的优点
PMMA1的物理性质
产品细节聚甲基丙烯酸甲酯的物理性能
聚甲基丙烯酸甲酯具有良好的综合机械性能,在通用塑料中位居前列。其拉伸、弯曲和压缩强度均高于聚烯烃,高于聚苯乙烯、聚氯乙烯等,冲击韧性较差。但它也比聚苯乙烯稍好一些。铸造本体聚合聚甲基丙烯酸甲酯板材(如航空有机玻璃板材)具有较高的拉伸、弯曲和压缩机械性能,可达到聚酰胺和聚碳酸酯等工程塑料的水平
PMMA的物理性能一般来说,聚甲基丙烯酸甲酯的拉伸强度可以达到50-77MPa,弯曲强度可以达到90-130MPa。这些性能数据的上限已经达到甚至超过了一些工程塑料。其断裂伸长率仅为
<2%-3%,因此其机械性能基本上是硬脆塑料,具有缺口敏感性,在应力作用下容易开裂,但断裂不像聚苯乙烯和普通无机玻璃那样尖锐和不均匀。40°C是二次转变温度,相当于侧基甲基开始移动的温度。高于40°C时,材料的韧性和延展性将得到改善。聚甲基丙烯酸甲酯表面硬度低,容易划伤
聚甲基丙烯酸甲酯的强度与应力时间有关,强度随应力时间的增加而降低。拉伸和取向后的聚甲基丙烯酸甲酯(取向有机玻璃)的力学性能得到明显改善,缺口敏感性也得到提高
聚甲基丙烯酸甲酯的耐热性不高。虽然其玻璃化转变温度达到104℃,但在不同的工作条件下,其最高连续使用温度在65℃~95℃之间变化,热变形温度约为96℃(1.18MPa),维卡软化点约为113℃。单体与甲基丙烯酸丙烯酯或丙烯酸乙二醇二酯共聚可提高耐热性。聚甲基丙烯酸甲酯的耐寒性也较差,脆化温度约为9.2°C。聚甲基丙烯酸甲酯的热稳定性适中,优于聚氯乙烯和聚甲醛,但不如聚烯烃和聚苯乙烯。热分解温度略高于270℃,流动温度约160℃。熔体加工温度范围很广
>Br/P>>聚甲基丙烯酸甲酯的热导率和比热容分别处于塑料的中间水平,为0.19W/cm。K和1464J/Kg。K
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Physical Properties Of PMMA1
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PMMA Plastic Material
Excellent transparency and outstanding aging resistance
PMMA has the advantages of light weight, low cost and easy molding.
Physical Properties Of PMMA1
Product Details
Physical properties of PMMA
Polymethyl methacrylate has good comprehensive mechanical properties and ranks in the forefront of general-purpose plastics. Its tensile, bending, and compressive strengths are all higher than polyolefins, and higher than polystyrene, polyvinyl chloride, etc., and have poor impact toughness. But it is also slightly better than polystyrene. The cast bulk polymerized polymethyl methacrylate sheet (such as aerospace plexiglass sheet) has higher tensile, bending, and compression mechanical properties, and can reach the level of engineering plastics such as polyamide and polycarbonate.
Physical properties of PMMA
Generally speaking, the tensile strength of polymethyl methacrylate can reach the level of 50-77MPa, and the bending strength can reach the level of 90-130MPa. The upper limit of these performance data has reached or even exceeded some engineering plastics. Its elongation at break is only
2%-3%, so the mechanical properties are basically hard and brittle plastics, and have notch sensitivity, and are easy to crack under stress, but the fracture is not as sharp and uneven as polystyrene and ordinary inorganic glass. 40°C is a secondary transition temperature, which is equivalent to the temperature at which the pendant methyl group starts to move. Above 40°C, the toughness and ductility of the material will be improved. Polymethyl methacrylate has low surface hardness and is easy to scratch.
The strength of polymethyl methacrylate is related to the stress time, and the strength decreases as the time increases. The mechanical properties of polymethyl methacrylate (oriented plexiglass) after stretching and orientation are obviously improved, and notch sensitivity is also improved.
The heat resistance of polymethyl methacrylate is not high. Although its glass transition temperature reaches 104°C, the maximum continuous use temperature varies between 65°C and 95°C with different working conditions, and the heat distortion temperature is about 96 ℃ (1.18MPa), Vicat softening point is about 113℃. The heat resistance can be improved by copolymerization of monomers with propylene methacrylate or ethylene glycol diester acrylate. The cold resistance of polymethyl methacrylate is also poor, and the embrittlement temperature is about 9.2°C. The thermal stability of polymethyl methacrylate is moderate, better than polyvinyl chloride and polyformaldehyde, but not as good as polyolefin and polystyrene. The thermal decomposition temperature is slightly higher than 270℃, and its flow temperature is about 160℃. There is a wide range of melt processing temperature.
The thermal conductivity and specific heat capacity of polymethyl methacrylate are in the middle level of plastics, respectively, 0.19W/CM.K and 1464J/Kg.K
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PMMA Plastic Material
Excellent transparency and outstanding aging resistance
PMMA has the advantages of light weight, low cost and easy molding.
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